Equilibrium Constants and its Significance

IMPORTANT

Equilibrium Constants and its Significance: Overview

This topic covers concepts, such as, Significance of Equilibrium Constant, Characteristics of Equilibrium Constant, Equilibrium Constant in Terms of Concentration(Kc) & Equilibrium Constant in Terms of Mole Fraction(Kx) etc.

Important Questions on Equilibrium Constants and its Significance

EASY
IMPORTANT

At constant temperature, the equilibrium constant  (Kp) for the decomposition reaction  N2O4(g)2NO2(g)  is expressed by Kp=4x21-x2P , where P = pressure, x = extent of decomposition. Which one of the following statements is true?

MEDIUM
IMPORTANT

At constant temperature, the equilibrium constant   ( K p ) for the decomposition reaction  N2O4(g)2NO2(g)  is expressed by kp=(4x2P)(1-x2) , where P = pressure, x = extent of decomposition. Which one of the following statements is true?

MEDIUM
IMPORTANT

For the reversible reaction,  N2(g)+3H2g2NH3(g) at 500°C, the value of  Kp is   1.44× 10 5 when partial pressure is measured in the atmosphere. The corresponding value of  Kc, with concentration in mol L-1, is: 

MEDIUM
IMPORTANT

For the reversible reaction N2(g)+3H2(g)2NH3(g) at 500°C , the value of Kp is  1.44× 10 5 when partial pressure is measured in atmosphere. The corresponding value of Kc, with concentration in mol litre-1, is:

MEDIUM
IMPORTANT

The Haber’s process for the formation of   NH 3 at 298 K is

 N2+3H22NH3;ΔH=46.0J.

Which of the following is the correct statement –

EASY
IMPORTANT

For the reversible reaction,   N 2 ( g )+3 H 2 (g)2N H 3 ( g ) at 500°C , the value of   K p is   1.44× 10 5 when partial pressure is measured in atmosphere. The corresponding value of   K c , with concentration in mole litre -1 , is –

MEDIUM
IMPORTANT

For the reversible reaction, N2(g)+3H2(g)2NH3(g) at 500°C , the value of Kp is 1.44× 10 5 , when partial pressure is measured in the atmosphere. The corresponding value of Kc, with the concentration in mole litre-1, is

EASY
IMPORTANT

For the reversible reaction,   N 2 ( g )+3 H 2 (g)2N H 3 ( g ) at 500°C , the value of   K p is   1.44× 10 5 when partial pressure is measured in atmosphere. The corresponding value of   K c , with concentration in mole litre -1 , is –

MEDIUM
IMPORTANT

For the chemical reaction   3X( g )+Y(g) X 3 Y( g ) , the amount of   X 3 Y at equilibrium is affected by –

EASY
IMPORTANT

What is the equilibrium expression for the reaction,   P 4 (s) + 5O 2 (g)   P 4 O 10 (s) ?

EASY
IMPORTANT

For the reaction equilibrium,   N 2 O 4 (g)   2NO 2 (g) the concentrations of   N 2 O 4 and   NO 2 at equilibrium are   4.8×1 0 -2 and1.2×1 0 -2 mol L -1 respectively. The value of Kc for the reaction is –

HARD
IMPORTANT

At 27°C1 mol of N2O4g placed in a container of volume 8.21 L, no dissociation takes place at this temperature. When the gas heated to 127°C, it is partially dissociated to NO2g and final pressure found to be 4.5 atm. Select the correct statement.

HARD
IMPORTANT

COF2 gas passed over a catalyst at 1000 °C comes to equilibrium:

2COF2 (g)CO2 (g)+CF4 (g)

Analysis of the equilibrium mixture (after quick cooling to freeze the equilibrium) shows that 500 mL of the equilibrium mixture (NTP) contains 300 mL (NTP) of COF2 and CO2. Taking the total pressure to be 10 atm, calculate Kp.

HARD
IMPORTANT

The freezing point of an aqueous saturated solution of I2 is  -0.0024 °C. More than this can dissolve in a KI solution because of the following equilibrium
I2(aq) + I-(aq)  I3(aq)-
0.1 M KI solution dissolves 12.5 g L-1 of I2. Calculate the equilibrium constant Kc for the above equilibrium. Assume molarity to be equal to molality and also assume that concentration of I in all saturated solutions is same. (Kf of water is 1.86 K molal-1, Molecular weight of I2 = 253.8 g/mol ) (Give answer upto nearest integer value.) 

EASY
IMPORTANT

If one-third of HI decomposes at a particular temperature, the value of equilibrium constant Kc for 2HIH2+I2 is

MEDIUM
IMPORTANT

1 L vessel contains 2 mol each of gases A, B, C and D at equilibrium. If 1 mol each of A and B are removed, Kc for A+BC+D will be

MEDIUM
IMPORTANT

If the equilibrium constants of the following equilibriums SO2+12O2SO3 and 2SO32SO2+O2 are given by K1 and K2, respectively, which of the following relations is correct?

HARD
IMPORTANT

For a reaction NH4COONH2(s)2NH3(g)+CO2(g), the equilibrium pressure is 3 atm. Kp for the reaction will be _____atm3.

HARD
IMPORTANT

0.1 mole of each of ethyl alcohol and acetic acid are allowed to react and at equilibrium, the acid was exactly neutralised by 100 mL of 0.85 N NaOH. If no hydrolysis of an ester is supposed to have undergone, the equilibrium constant is y×10-3. Calculate the value of y?

HARD
IMPORTANT

An air sample containing 21:79 of O2 and N2 (mole ratio) is heated to 2400°C. If the mole percent of NO at equilibrium is 1.8%, calculate Kp for the reaction N2+O22NO.

Give your answer after multiplying by 105 and round off up to nearest integer.